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排序方式: 共有750条查询结果,搜索用时 15 毫秒
81.
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All‐Polymer Solar Cells Based on a Conjugated Polymer Containing Siloxane‐Functionalized Side Chains with Efficiency over 10% 下载免费PDF全文
Baobing Fan Lei Ying Peng Zhu Feilong Pan Feng Liu Junwu Chen Fei Huang Yong Cao 《Advanced materials (Deerfield Beach, Fla.)》2017,29(47)
A novel wide‐bandgap conjugated copolymer based on an imide‐functionalized benzotriazole building block containing a siloxane‐terminated side‐chain is developed. This copolymer is successfully used to fabricate highly efficient all‐polymer solar cells (all‐PSCs) processed at room temperature with the green‐solvent 2‐methyl‐tetrahydrofuran. When paired with a naphthalene diimide‐based polymer electron‐acceptor, the all‐PSC exhibits a maximum power conversion efficiency (PCE) of 10.1%, which is the highest value so far reported for an all‐PSC. Of particular interest is that the PCE remains 9.4% after thermal annealing at 80 °C for 24 h. The resulting high efficiency is attributed to a combination of high and balanced bulky charge carrier mobility, favorable face‐on orientation, and high crystallinity. These observations indicate that the resulting copolymer can be a promising candidate toward high‐performance all‐PSCs for practical applications. 相似文献
83.
阴离子表面活性剂缔合亚甲基蓝光度法测定硫化物的研究 总被引:2,自引:0,他引:2
在酸性介质中,硫化物与对氨基二甲基苯胺形成亚甲蓝,并与十二烷基磺酸钠缔合,可使吸光度提高.该缔和物于660nm处有最大吸收,摩尔吸光系数为120×104L·mol-1·cm-1,S2-含量在0~24μg/25mL范围内符合比尔定律.该方法用于天然水中微量硫化物的测定,结果满意 相似文献
84.
介绍了硅氧烷与丙烯酸树脂的原位、接枝聚合方法,改性过程中水、酸、催化剂等的影响。研究结果表明,原位聚合改性大大提高了丙烯酸树脂的耐热性、耐溶剂性 相似文献
85.
Koen Nickmans Gerardus M. Bögels Carlos Sánchez‐Somolinos Jeffrey N. Murphy Philippe Leclère Ilja K. Voets Albertus P. H. J. Schenning 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(33)
While self‐assembled molecular building blocks could lead to many next‐generation functional organic nanomaterials, control over the thin‐film morphologies to yield monolithic sub‐5 nm patterns with 3D orientational control at macroscopic length scales remains a grand challenge. A series of photoresponsive hybrid oligo(dimethylsiloxane) liquid crystals that form periodic cylindrical nanostructures with periodicities between 3.8 and 5.1 nm is studied. The liquid crystals can be aligned in‐plane by exposure to actinic linearly polarized light and out‐of‐plane by exposure to actinic unpolarized light. The photoalignment is most efficient when performed just under the clearing point of the liquid crystal, at which the cylindrical nanostructures are reoriented within minutes. These results allow the generation of highly ordered sub‐5 nm patterns in thin films at macroscopic length scales, with control over the orientation in a noncontact fashion. 相似文献
86.
Flexible Hard Coating: Glass‐Like Wear Resistant,Yet Plastic‐Like Compliant,Transparent Protective Coating for Foldable Displays 下载免费PDF全文
Gwang‐Mun Choi Jungho Jin Dahye Shin Yun Hyeok Kim Ji‐Hoon Ko Hyeon‐Gyun Im Junho Jang Dongchan Jang Byeong‐Soo Bae 《Advanced materials (Deerfield Beach, Fla.)》2017,29(19)
A flexible hard coating for foldable displays is realized by the highly cross‐linked siloxane hybrid using structure–property relationships in organic–inorganic hybridization. Glass‐like wear resistance, plastic‐like flexibility, and highly elastic resilience are demonstrated together with outstanding optical transparency. It provides a framework for the application of siloxane hybrids in protective hard coatings with high scratch resistance and flexibility for foldable displays. 相似文献
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Yuan Meng Weijing Xu Maureen R. Newman Danielle S. W. Benoit Mitchell Anthamatten 《Advanced functional materials》2019,29(38)
Polysiloxane elastomers represent a widely utilized soft material with excellent rubber‐like elasticity, biocompatibility, and biodurability; however, there is a lack of an effective and straightforward approach to manipulate the material's viscoelastic response. A facile hydrosilylation reaction is employed to integrate ureidopyrimidinone hydrogen‐bonding side‐groups into linear and crosslinked siloxane polymers to achieve biocompatible soft materials with a highly tunable viscoelastic relaxation timescale. Stacking of H‐bonded moieties is avoided in the designed macromolecular architectures with tight, side‐groups substituents. The obtained siloxane network features the presence of both covalent crosslinks and truly thermoreversible crosslinks, and can be formulated across a broad material design space including elastic solids, recoverable viscoelastic solids, and viscous liquids. The elastomers exhibit unique temperature‐dependent shape‐memory capability and show good cytocompatibility. Importantly, a deformed material's shape‐recovery occurs regardless of external triggering, and through manipulation of network formulations, the shape‐recovery timescale can be easily tuned from seconds to days, opening new possibilities for biomedical, healthcare, and soft material applications. 相似文献
90.